Tuesday, February 22, 2011

Feb 21 - Enthalpy Calculations

H : Energy change in the reaction. Units - kJ/mole


Eg.  CH+ 2O-->  CO2 + 2H2O  + 812kJ
H can be expressed as:
-812kJ/1mole CH4 or -812kJ/2mole O2 = -406kJ/1mole O2
-812kJ/1mole CO2 or -812kJ/2mole H2O = -406kJ/1mole H2O
Ex. calculate the energy released when 0.35 moles of  H2O is produced
0.35 moles H2O * (-406kJ/1mole H2O) = -142.1kJ
                             2Sig Fig                    = -140kJ
Ex. How many moles of CH4 are needed to produce 2100kJ of energy?
2100kJ * (1mole CH4/-812kJ) = -2.586
                                                = -2.6
                                                is  2.6 since mole cannot be negative

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